/Resources 147 0 R An example is shown in Figure 5.13. B, Vol 20B, 1989, p 445–473, M. Hillert, Phase Equilibria Phase Diagrams and Phase Transformations—Their Thermodynamic Basis, Cambridge University Press, 1998, L. Kaufman, Ed., User Applications of Alloy Phase Diagrams, ASM International, 1987, A.M. Alper, Ed., Phase Diagrams in Advanced Ceramics, Academic Press, 1995, T.I. This is a preview of subscription content, log in to check access. 28 0 obj 1, 1985, I. Barin, Thermochemical Data of Pure Substances, VCH, 1993, F. Larché and J.W. In addition, intermittent sliding induces a cyclic evolution of the electrochemical state of the surface in the sliding track. Chem., Vol 89, 1985, p 1323, M. Martin and H. Schmalzried, Ber. Barry, Ed., Chemical Thermodynamics in Industry: Models and Computations, Critical Reports on Applied Chemistry, Vol 8, Society of Chemical Industry/Blackwell Scientific Publications, 1985, S.A. Newman, Ed., Thermodynamics of Aqueous Systems with Industrial Applications, Symposium series 133, American Chemical Society, 1980, M. Pourbaix, Atlas of Electrochemical Equilibria, CEBELCOR and Pergamon Press, 1965, P.B. << Figure 8. The chemical potential of dep_elt is computed from the target composition energy. Forum, Vol 66–69, 1989, p 1497–1502, R.C.J. /Type /Page Am. Sci., Vol 21, 1986, p 3078; Vol 21, 1986, p 3085; Vol 22, 1986, p4233, H. Schmalzried, J. Chem. At the phase boundaries of the Fe-N system the chemical potentials of nitrogen 24 are equal for the solid and the gaseous phases co-existing in equilibrium. In the absence of an electrochemical steady state, it should be noted that a number of electrochemical methods used for the study of corrosion cannot be implemented in tribocorrosion. /CropBox [0.0 0.0 482.0 680.0] endstream /Type /Page Mehan, A.M. Davis, and E.L. Hall, Metall. Metall. /XObject << K. Morita, N. Sano, in Fundamentals of Metallurgy, 2005. Both diagrams are helpful in predicting a final product and in verifying the processing conditions. Google Scholar, L. Kaufman and H. Bernstein, Computer Calculation of Phase Diagrams, Academic Press, 1970, A.D. Pelton and W.T. /Rotate 0 Depending on the particular graph of the chemical potential, the mixture might be heterogeneous. /Parent 2 0 R endobj Google Scholar, M. E. Brito, H. Yokoyama, Y. Hirotsu, and Y. Mutoh, ISIJ Int., Vol 29, 1989, p 253, W. Oelson and H. Samson-Himmelstjerna, Mitt. stream 1), 1978, p 35–53; Vol 3 (No. Soc., Vol 136 (No. uuid:a3bd0344-fdda-11ec-0000-8828ed08e80b ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9780444527929500129, URL: https://www.sciencedirect.com/science/article/pii/B0080437486010987, URL: https://www.sciencedirect.com/science/article/pii/B9781855739277500030, URL: https://www.sciencedirect.com/science/article/pii/B978085709592350001X, URL: https://www.sciencedirect.com/science/article/pii/B9780857095442500051, URL: https://www.sciencedirect.com/science/article/pii/B9780444527929500105, URL: https://www.sciencedirect.com/science/article/pii/B9780444527929500075, URL: https://www.sciencedirect.com/science/article/pii/B9780444527929500099, URL: https://www.sciencedirect.com/science/article/pii/B9780815514374500151, URL: https://www.sciencedirect.com/science/article/pii/B9780857095404500144, Fundamentals: Physical Methods, Theoretical Analysis, and Case Studies, Phase diagrams, phase transformations, and the prediction of metal properties, In this chapter, fundamentals of chemical, Thermodynamics and kinetics of gas and gas–solid reactions, Thermochemical Surface Engineering of Steels, The use of nanotechnology to improve the bulk and surface properties of steel for structural applications, Nanotechnology in Eco-Efficient Construction, This chapter summarizes several aspects of deposition of alloys. van Loo, and G. de With, J. Waldfried Plieth, in Electrochemistry for Materials Science, 2008. 23 0 obj /CropBox [0.0 0.0 482.0 680.0] /Contents [113 0 R 114 0 R 115 0 R 116 0 R] /Parent 2 0 R /CropBox [0.0 0.0 482.0 680.0] Soc., Vol 72, 1989, p 152, H. Yokokawa, N. Sakai, T. Kawada, and M. Dokiya, J. Electrochem. Sliding tests can also be performed in such a way that the counter-body slides for one rotation and then stays immobile for a certain time known as off-time, toff. 4), 1992, p 170–173, H. Yokokawa, T. Kawada, and M. Dokiya, Denki Kagaku, Vol 56, 1988, p 751, H. Yokokawa, N. Sakai, T. Kawada, and M. Dokiya, J. /Filter /FlateDecode /Parent 2 0 R Anal. endobj Sci. At higher potentials a further oxidation to NiO2 with a new decrease in current is observed. One of the best demonstrations of the application of thermodynamics to corrosion phenomena is provided by the potential-pH plots or Pourbaix diagrams.